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Gasoline consists of various hydrocarbons (compounds consisting of hydrogen and carbon atoms) derived from petroleum. The ability to evaporate under engine conditions determines which hydrocarbons can be used in gasoline. The ability to evaporate is called volatility, and will be discussed later. Because crude petroleum consists of hydrocarbons both more and less volatile than gasoline, gasoline must be separated from petroleum by a process called distillation. Distillation, however, provides an insufficient amount and quality of gasoline. So gasoline production is supplemented with more sophisticated refinery processes. 

These refining processes take the less and more volatile hydrocarbons found in petroleum, and turn them into hydrocarbons that have not only the correct volatility, but also other desirable characteristics necessary for good engine performance. These characteristics are discussed later. Finished gasoline, then, is a blend of hydrocarbons having a similar volatility range, made from distillation and refining processes. There are over 200 individual hydrocarbons, as well as trace concentrations of other compounds, naturally present in petroleum. To these are added specialty chemicals that add to or enhance the performance of the hydrocarbons.  

Composition and properties of gasoline are determined by the crude oil from which it was derived, what refining processes were used to produce the gasoline, and the nature of the additives used to add to or enhance the gasoline's performance.  

By characterizing certain physical, chemical and combustion properties of gasoline, we can predict (in part) how it will perform in internal combustion engines. These properties are summarized in the American Society for Testing and Materials Standard Specification for Automotive Spark-Ignition Engine Fuel (ASTM Designation D 4814). ASTM is a technical organization that develops a consensus of voluntary performance standards for materials and products. This Standard Specification applies to almost all gasoline sold in the United States. Other gasoline properties not specified in ASTM D 4814, which are also important to performance, are summarized in Table 3 at the end of this handbook.  

TABLE 1:  

REFINING PROCESSES FOR GASOLINE MANUFACTURE
Alkylation:  
Conversion of small, gaseous hydrocarbons to larger, liquid hydrocarbons. 
Catalytic Cracking:  
Conversion of larger, high-boiling hydrocarbons to smaller, more volatile compounds. 
Hydrocracking 
Catalytic cracking in hydrogen atmosphere.
lsomerization:  
Converts low-octane hydrocarbons to higher octane.
Re-forming:  
Catalytic process to change hydrocarbon structure to more desirable (higher octane) compounds. 

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